basic knowledge of conductometry titrations and its principle, instrumentation, & advantages and disdavantages of these titrations. Conductometry DR. . 3Principle The main principle involved in this method is that the movement of the ions creates the electrical. Conductometry-. Introduction. Ohm’s law. Conductometric measurements. Factor affecting conductivity. Application of conductometry. tometric titration.

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All these are operated by the battery. Initially the plot shows the decrease in the conductivity and then shows the increase in the conductivity.

Conductometry – Wikipedia

The solutions are compulsory diluted for the measurements. Headphone is used for the detection of the conductance difference. What is the theory of conductometry? On passing the current, chloroplatinic acid under goes electrolysis and the electrodes are blackened.

In this condcutometry, the primary aromatic amine is reacted with the sodium nitrite in acidic medium to form a diazonium salt. These are commonly employed by dipping in the analyte solution.

In another case, the titration will form two precipitates. These are extremely weak and cannot be analysed using normal titrimetric methods. Fritz first used this method to distinguish the aromatic and aliphatic amines by prinfiple the perchloric acid as titrant.

Pharmaceutical Analysis by P. D. Chaithanya Sudha

Then the plot between the conductivity cpnductometry the volume of the titrant shows the plateau. Weak acid with a strong base: Weak acid with strong base titration curve.

After the equivalence point, the addition of the excess of the titrant shows the stability in the conductivity. It was also around this time when Willis Whitney, who was studying the interactions of sulfuric acid and chromium sulfate complexes, found the first conductometric endpoint.


Lowitz first prepared the moisture-free solvents non-aqueous solvents. In this type, the cell is dipped in the sample solution to measure the conductance in the titrations.

Weak acid with weak base titration curve.


Conductimetry temperature is maintained constant with the help of the thermostat. Potassium chloride is titrated with the precipitating agent such as the silver nitrate solution. This page was last edited on 16 Decemberat This contribution in case of a strong acid-strong base is negligible and is not considered there. No need of indicator. The basicity is defined as the number of carboxylic acid groups attached to the molecules. Then the molar conductivity is defined as the conductivity due to 1 mole and it is expressed by the following formula: Conductometdy each amount of NaOH added equivalent amount of hydrogen ions is removed.

The equivalence point is the point at which the conductivity undergoes a sudden change. The following are the different bridges used for the measurement of the conductoetry The conductance is defined as the reciprocal of the resistance.

It is composed of pair of electrodes placed at a constant conductoometry. The sample solution is placed on the cell which is composed of platinum electrodes. Appropriate for the dilute solutions.

This method is first used in the determination of dyes. The theory is mainly based on Ohm’s law which states that the current I is directly proportional to the electromotive force E and inversely proportional to the resistance R of the conductor: The acetic acid is dissociated and it combines with the ammonium ion after dissociation of the ammonium hydroxide.


In Folin and Flanders titrated the acidic substances by using the non-aqueous solvents such as benzene, chloroform and chloroform-methanol mixture. Then the cell is connected to the resistor box R and the alternating current is passed through the cell with the help of induction coil. The weak acid such as the acetic acid is titrated with the weak base such as ammonium hydroxide.

Consequently, in the titration of a strong acid with a strong base, the conductance has a minimum at the equivalence point. The titration of the ferrous ions with the dichromate ions. What are the different methods of conductivity measurements? Conductometry free pharmacy study material pharmaceutical analysis pharmaceutical analysis lecture notes. By using this site, you agree to the Terms of Use and Privacy Policy. Unsourced material may be challenged and removed.

2. Conductometry – Pharmaceutical Analysis [Book]

Used in the determination of the purity of the water. That is the increase in the size of the ions increases the conductivity. These conductivity cells are made up of glass. This consists of the electrodes placed at a large distance and is used for the measurement of the high conductance.

The hydrogen ions show sharp decrease in the conductivity.